Search for: All records

The millimeter/submillimeter-wave spectrum of the SiP radical (X 2 Π i ) has been recorded using direct absorption spectroscopy in the frequency range of 151–532 GHz. SiP was synthesized in an AC discharge from the reaction of SiH 4 and gas-phase phosphorus, in argon carrier gas. Both spin–orbit ladders were observed. Fifteen rotational transitions were measured originating in the Ω = 3/2 ladder, and twelve in the Ω = 1/2 substate, each exhibiting lambda doubling and, at lower frequencies, hyperfine interactions from the phosphorus nuclear spin of I = 1/2. The lambda-doublets in the Ω = 1/2 levels appeared to be perturbed at higher J, with the f component deviating from the predicted pattern, likely due to interactions with the nearby excited A 2 Σ + electronic state, where ΔE Π-Σ ∼ 430 cm −1 . The data were analyzed using a Hund’s case a β Hamiltonian and rotational, spin–orbit, lambda-doubling, and hyperfine parameters were determined. A 2 Π/ 2 Σ deperturbation analysis was also performed, considering spin–orbit, spin-electronic, and L-uncoupling interactions. Although SiP is clearly not a hydride, the deperturbed parameters derived suggest that the pure precession hypothesis may be useful in assessing the 2 Π/ 2 Σ interaction. Interpretation of the Fermi contact term, b F , the spin-dipolar constant, c, and the nuclear spin-orbital parameter, a, indicates that the orbital of the unpaired electron is chiefly p π in character. The bond length in the v = 0 level was found to be r 0 = 2.076 Å, suggestive of a double bond between the silicon and phosphorus atoms. 

The millimeter-wave spectrum of the SiP radical (X²Π_i) has been measured in the laboratory for the first time using direct-absorption methods. SiP was created by the reaction of phosphorus vapor and SiH₄in argon in an AC discharge. Fifteen rotational transitions (J+ 1 ←J) were measured for SiP in the Ω = 3/2 ladder in the frequency range 151–533 GHz, and rotational, lambda doubling, and phosphorus hyperfine constants determined. Based on the laboratory measurements, SiP was detected in the circumstellar shell of IRC+10216, using the Submillimeter Telescope and the 12 m antenna of the Arizona Radio Observatory at 1 mm and 2 mm, respectively. Eight transitions of SiP were searched: four were completely obscured by stronger features, two were uncontaminated (J= 13.5 → 12.5 and 16.5 → 15.5), and two were partially blended with other lines (J= 8.5 → 7.5 and 17.5 → 16.5). The SiP line profiles were broader than expected for IRC+10216, consistent with the hyperfine splitting. From non-LTE radiative transfer modeling, SiP was found to have a shell distribution with a radius ∼300R_*, and an abundance, relative to H₂, off∼ 2 × 10⁻⁹. From additional modeling, abundances of 7 × 10⁻⁹and 9 × 10⁻¹⁰were determined for CP and PN, respectively, both located in shells at 550–650R_*. SiP may be formed from grain destruction, which liberates both phosphorus and silicon into the gas phase, and then is channeled into other P-bearing molecules such as PN and CP.

 

The rise of the Halemaʻumaʻu lava lake in 2013–2018 to depths commonly 40 meters or less below the rim of the vent was an excellent opportunity to study outgassing and the link to associated eruptive activity. We use videography to investigate the rise and bursting of bubbles through the free surface of the lake in 2015. We focus on low-energy explosive activity (spattering) in which the ascent and bursting of meter-sized, mechanically decoupled bubbles trigger the ejection of fluidal bombs to tens of meters above the free surface. A decay in initial pyroclast velocity with time follows the same functional form as that observed for ejecta at Stromboli (Italy), suggesting a similar bubble-burst mechanism. 

The rise of the Halemaʻumaʻu lava lake in 2013–2018 to depths commonly 40 meters or less below the rim of the vent was an excellent opportunity to study outgassing and the link to associated eruptive activity. We use videography to investigate the rise and bursting of bubbles through the free surface of the lake in 2015. We focus on low-energy explosive activity (spattering) in which the ascent and bursting of meter-sized, mechanically decoupled bubbles trigger the ejection of fluidal bombs to tens of meters above the free surface. A decay in initial pyroclast velocity with time follows the same functional form as that observed for ejecta at Stromboli (Italy), suggesting a similar bubble-burst mechanism. We also find that the upward velocity of the bubble crust as it bursts is around 2.5 times higher than the velocity of the bubble as it rises through the lake surface, indicating that the bubbles are over-pressurized. Prior to bursting, bubbles emerge at velocities of 4 to 14 meters per second, suggesting rise from depths of at least tens of meters but unaffected by the deeper circulation of the lava lake. We identify three styles of bubble bursting: (1) isolated, widely spaced, single bursts, (2) recurring clusters of discrete bubbles, and (3) prolonged episodes of overlapping bubble bursts along elongate narrow sources typically parallel to the margins of the lava lake. We call these styles of bursting isolated events, clusters, and prolonged episodes, respectively. The frequency of bubble bursting and the mass fluxes of gas and pyroclasts increase from styles 1 to 3. The intensity (mass eruption rate) for single bubble bursts ranges from 280 to 3,500 kilograms per second. The total erupted mass of pyroclasts for a single burst is <4,000 kilograms (kg) and for a single well-constrained prolonged episode is about 107 kg. These numbers place the observed spattering at the lowest end of basaltic explosivity in terms of erupted mass (that is, magnitude). Most ejecta fell back into the crater; only strands of Pele’s hair rose to heights where they could be advected downwind from the vent.